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Reaction Kinetics in Polymer Melts
We study the reaction kinetics of end-functionalized polymer chains dispersed in an unreactive polymer melt. Starting from an infinite hierarchy of coupled equations for many-chain correlation functions, a closed equation is derived for the 2nd order rate constant k after postulating simple physical bounds. Our results generalize previous 2-chain treatments (valid in dilute reactants limit) by ...
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ژورنال
عنوان ژورنال: Kobunshi
سال: 1971
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.20.450